Abstract
The water-proton fast exchange between the vicinity of the ferric haemiron and bulk solvent in horseradish peroxidase solutions at neutral pH has been directly verified by measuring the proton magnetic relaxation times of the aliphatic protons from ethanediol in an otherwise deuterated solution. The implications of this finding are discussed with regard to the stereochemistry of the haem-surrounding.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 1154-1159 |
| Number of pages | 6 |
| Journal | Biochemical and Biophysical Research Communications |
| Volume | 66 |
| Issue number | 4 |
| DOIs | |
| State | Published - Oct 27 1975 |
| Externally published | Yes |
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ASJC Scopus subject areas
- Biochemistry
- Biophysics
- Molecular Biology
Cite this
The haem-environment in horseradish peroxidase as seen by proton magnetic relaxation. / Vuk-Pavlović, S.; Benko, B.
In: Biochemical and Biophysical Research Communications, Vol. 66, No. 4, 27.10.1975, p. 1154-1159.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - The haem-environment in horseradish peroxidase as seen by proton magnetic relaxation
AU - Vuk-Pavlović, S.
AU - Benko, B.
PY - 1975/10/27
Y1 - 1975/10/27
N2 - The water-proton fast exchange between the vicinity of the ferric haemiron and bulk solvent in horseradish peroxidase solutions at neutral pH has been directly verified by measuring the proton magnetic relaxation times of the aliphatic protons from ethanediol in an otherwise deuterated solution. The implications of this finding are discussed with regard to the stereochemistry of the haem-surrounding.
AB - The water-proton fast exchange between the vicinity of the ferric haemiron and bulk solvent in horseradish peroxidase solutions at neutral pH has been directly verified by measuring the proton magnetic relaxation times of the aliphatic protons from ethanediol in an otherwise deuterated solution. The implications of this finding are discussed with regard to the stereochemistry of the haem-surrounding.
UR - http://www.scopus.com/inward/record.url?scp=0016769010&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0016769010&partnerID=8YFLogxK
U2 - 10.1016/0006-291X(75)90479-9
DO - 10.1016/0006-291X(75)90479-9
M3 - Article
VL - 66
SP - 1154
EP - 1159
JO - Biochemical and Biophysical Research Communications
JF - Biochemical and Biophysical Research Communications
SN - 0006-291X
IS - 4
ER -