The haem-environment in horseradish peroxidase as seen by proton magnetic relaxation

S. Vuk-Pavlović; B. Benko

doi:10.1016/0006-291X(75)90479-9

The haem-environment in horseradish peroxidase as seen by proton magnetic relaxation

S. Vuk-Pavlović, B. Benko

Hematology

Research output: Contribution to journal › Article › peer-review

21 Scopus citations

Abstract

The water-proton fast exchange between the vicinity of the ferric haemiron and bulk solvent in horseradish peroxidase solutions at neutral pH has been directly verified by measuring the proton magnetic relaxation times of the aliphatic protons from ethanediol in an otherwise deuterated solution. The implications of this finding are discussed with regard to the stereochemistry of the haem-surrounding.

Original language	English (US)
Pages (from-to)	1154-1159
Number of pages	6
Journal	Biochemical and Biophysical Research Communications
Volume	66
Issue number	4
DOIs	https://doi.org/10.1016/0006-291X(75)90479-9
State	Published - Oct 27 1975

ASJC Scopus subject areas

Biophysics
Biochemistry
Molecular Biology
Cell Biology

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10.1016/0006-291X(75)90479-9

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title = "The haem-environment in horseradish peroxidase as seen by proton magnetic relaxation",

abstract = "The water-proton fast exchange between the vicinity of the ferric haemiron and bulk solvent in horseradish peroxidase solutions at neutral pH has been directly verified by measuring the proton magnetic relaxation times of the aliphatic protons from ethanediol in an otherwise deuterated solution. The implications of this finding are discussed with regard to the stereochemistry of the haem-surrounding.",

author = "S. Vuk-Pavlovi{\'c} and B. Benko",

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AU - Vuk-Pavlović, S.

AU - Benko, B.

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N2 - The water-proton fast exchange between the vicinity of the ferric haemiron and bulk solvent in horseradish peroxidase solutions at neutral pH has been directly verified by measuring the proton magnetic relaxation times of the aliphatic protons from ethanediol in an otherwise deuterated solution. The implications of this finding are discussed with regard to the stereochemistry of the haem-surrounding.

AB - The water-proton fast exchange between the vicinity of the ferric haemiron and bulk solvent in horseradish peroxidase solutions at neutral pH has been directly verified by measuring the proton magnetic relaxation times of the aliphatic protons from ethanediol in an otherwise deuterated solution. The implications of this finding are discussed with regard to the stereochemistry of the haem-surrounding.

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The haem-environment in horseradish peroxidase as seen by proton magnetic relaxation

Abstract

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