Abstract
Our route to the preparation of doped glassy carbon solids allows the incorporation of elements in a controlled manner, both in type of element(s) and level of doping. The introduction of dopants into carbon electrodes may profoundly affect their electrochemical behavior with respect to stability, adsorption, and catalysis. Just as dopants in silicon provided materials for the electronic revolution, controlled doping of glassy carbon materials may radically improve their electrochemical behavior. Our initial synthetic efforts have been focused on the preparation of solids doped with main group elements: a low temperature route using diacetylenic polymer precursors to these modified glassy carbon materials. The physical properties of these materials, including electrical resistivity, thermal stability, microscopic structure, density, and elastic modulus were examined. We have prepared solids which incorporate silicon, chlorine and fluorine.
| Original language | English (US) |
|---|---|
| Title of host publication | Polymeric Materials Science and Engineering, Proceedings of the ACS Division of Polymeric Materials Science and Engineering |
| Publisher | Publ by ACS |
| Pages | 921-923 |
| Number of pages | 3 |
| Volume | 61 |
| State | Published - 1989 |
| Externally published | Yes |
| Event | Proceedings of the ACS Division of Polymeric Materials: Science and Engineering - Miami Beach, FL, USA Duration: Sep 11 1989 → Sep 18 1989 |
Other
| Other | Proceedings of the ACS Division of Polymeric Materials: Science and Engineering |
|---|---|
| City | Miami Beach, FL, USA |
| Period | 9/11/89 → 9/18/89 |
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ASJC Scopus subject areas
- Chemical Engineering (miscellaneous)
- Polymers and Plastics
Cite this
Doped glassy carbon materials (DGC). Their synthesis and investigation of their properties. / Callstrom, Matthew R; McCreery, Richard L.; Alsmeyer, Daniel C.; Neenan, Thomas X.
Polymeric Materials Science and Engineering, Proceedings of the ACS Division of Polymeric Materials Science and Engineering. Vol. 61 Publ by ACS, 1989. p. 921-923.Research output: Chapter in Book/Report/Conference proceeding › Conference contribution
}
TY - GEN
T1 - Doped glassy carbon materials (DGC). Their synthesis and investigation of their properties
AU - Callstrom, Matthew R
AU - McCreery, Richard L.
AU - Alsmeyer, Daniel C.
AU - Neenan, Thomas X.
PY - 1989
Y1 - 1989
N2 - Our route to the preparation of doped glassy carbon solids allows the incorporation of elements in a controlled manner, both in type of element(s) and level of doping. The introduction of dopants into carbon electrodes may profoundly affect their electrochemical behavior with respect to stability, adsorption, and catalysis. Just as dopants in silicon provided materials for the electronic revolution, controlled doping of glassy carbon materials may radically improve their electrochemical behavior. Our initial synthetic efforts have been focused on the preparation of solids doped with main group elements: a low temperature route using diacetylenic polymer precursors to these modified glassy carbon materials. The physical properties of these materials, including electrical resistivity, thermal stability, microscopic structure, density, and elastic modulus were examined. We have prepared solids which incorporate silicon, chlorine and fluorine.
AB - Our route to the preparation of doped glassy carbon solids allows the incorporation of elements in a controlled manner, both in type of element(s) and level of doping. The introduction of dopants into carbon electrodes may profoundly affect their electrochemical behavior with respect to stability, adsorption, and catalysis. Just as dopants in silicon provided materials for the electronic revolution, controlled doping of glassy carbon materials may radically improve their electrochemical behavior. Our initial synthetic efforts have been focused on the preparation of solids doped with main group elements: a low temperature route using diacetylenic polymer precursors to these modified glassy carbon materials. The physical properties of these materials, including electrical resistivity, thermal stability, microscopic structure, density, and elastic modulus were examined. We have prepared solids which incorporate silicon, chlorine and fluorine.
UR - http://www.scopus.com/inward/record.url?scp=0024886245&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0024886245&partnerID=8YFLogxK
M3 - Conference contribution
VL - 61
SP - 921
EP - 923
BT - Polymeric Materials Science and Engineering, Proceedings of the ACS Division of Polymeric Materials Science and Engineering
PB - Publ by ACS
ER -